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General Organic Chemistry III: Reaction Intermediates
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Reaction energy profiles, kinetic vs thermodynamic control
NEET level
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Difficulty 1 of 3
g3172
Naphthalene is sulfonated with concentrated
H
X
2
SO
X
4
at
80
∘
C
for a short time. The major product is
A
naphthalen-1-ol
B
naphthalene-2-carboxylic acid
C
naphthalene-2-sulfonic acid
D
naphthalene-1-sulfonic acid
Answer: D
At
80
∘
C
the reaction is under kinetic control, and attack at C-1 is faster. The product is naphthalene-1-sulfonic acid.
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