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JEE Main levelSingle correct optionDifficulty 2 of 3g3093

Singlet dichlorocarbene is much less reactive and more selective than singlet . The main reason is that

  1. Alone pairs on the chlorine atoms donate into the empty orbital of the carbene carbon
  2. Bchlorine atoms make the carbene carbon more electron-rich through a effect
  3. Cthe C-Cl bonds are non-polar
  4. D is a triplet with two unpaired electrons

Answer: A

The empty orbital on the carbene carbon of the singlet is the electrophilic site. Chlorine lone pairs overlap with it (a effect) and partly fill it, which stabilises the carbene and lowers its reactivity. Chlorine is , not , and has a singlet ground state, so the other statements are wrong.
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