MolSynapsequestion bank
MolSynapse / Question bank / General Organic Chemistry III: Reaction Intermediates / Carbanions and enolates
JEE Main levelSingle correct optionDifficulty 2 of 3g3068

Arrange the carbanions in decreasing order of stability (usual NCERT-level argument based on hybridisation and alkyl substitution): , , ,

  1. A
  2. B
  3. C
  4. D

Answer: B

Stability increases with s-character of the orbital holding the lone pair: (50%) > (33%) > (25%). Among the two anions, the tertiary one is destabilised by three +I alkyl groups, so ethyl is more stable than tert-butyl. This gives the stated order.
Practice General Organic Chemistry III: Reaction Intermediates More on Carbanions and enolates

More questions on Carbanions and enolates