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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3g3052

Select the correct statement(s) about the allyl cation .

  1. AThe pi system contains four electrons.
  2. BAll three carbons are hybridised.
  3. CThe two C-C bonds have equal length.
  4. DThe central carbon carries essentially no positive charge.

Answer: B, C, D

Two equivalent resonance forms place the charge on C1 and C3 alone. The delocalisation makes the two C-C bonds identical and requires three parallel orbitals on three carbons. Only two pi electrons are in the system, since the carbocation has an empty orbital.
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