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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3g3047

Select the correct statement(s) about the 3,3-dimethylbutan-2-yl cation, .

  1. AA 1,2-hydride shift can convert it to a tertiary cation.
  2. BThe number of alpha hydrogens (excluding the hydrogen on the cationic carbon itself) is 3.
  3. CThe rearranged cation is more stable than the starting cation.
  4. DA 1,2-methyl shift converts it to the 2,3-dimethylbutan-2-yl cation, a tertiary cation.

Answer: B, C, D

The neighbouring carbon has no hydrogen, so only a methyl shift is possible (statement 3 is false). The only alpha hydrogens are those of the on the other side, so 3. Methyl shift gives the tertiary , which is more stable.
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