NEET levelSingle correct optionDifficulty 1 of 3g3005
The benzyl cation CX6HX5CHX2X+ is much more stable than the ethyl cation CHX3CHX2X+ mainly because:
Athe cationic carbon is sp3 hybridised
Bthe positive charge is delocalised into the benzene ring by resonance
Cphenyl is a strongly electron-withdrawing group by −I effect
Dthe benzyl cation is aromatic because of the CHX2X+ group alone
Answer: B
The empty p orbital of the CHX2X+ carbon overlaps with the ring π system, so the charge is spread over the ortho and para carbons. The ethyl cation has only hyperconjugation with 3 alpha hydrogens.