JEE Main levelSingle correct optionDifficulty 2 of 3g2186
How many of the following compounds can undergo keto-enol tautomerism? CHX3CHO, CX6HX5CHO, CX6HX5COCHX3, (CHX3)X3C−CO−C(CHX3)X3, CHX3COCH(CHX3)X2, HCHO
A3
B2
C4
D5
Answer: A
Enolisation needs an alpha hydrogen. CHX3CHO (yes), CX6HX5CHO (no), CX6HX5COCHX3 (yes, the methyl hydrogens), (CHX3)X3C−CO−C(CHX3)X3 (no, the alpha carbons are quaternary), CHX3COCH(CHX3)X2 (yes), HCHO (no). Count =3.