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NEET levelSingle correct optionDifficulty 1 of 3g2113

Terminal alkynes () can be converted almost completely into sodium alkynides by which of the following?

  1. AAqueous
  2. BAqueous
  3. C in liquid ammonia
  4. DAqueous

Answer: C

A reaction goes forward when the acid is stronger than the conjugate acid of the base. (conjugate acid of ) has , much higher than 25, so deprotonates the alkyne completely. Water (15.7) and (6.4) are far stronger acids than the alkyne, so and cannot do it.
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