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General Organic Chemistry I: Electronic Effects
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Aromaticity, antiaromaticity and Huckel rule
JEE Main level
Single correct option
Difficulty 2 of 3
g1134
Which one of the following is aromatic?
A
cyclobutadiene
B
cyclopentadienyl cation (cyclopenta-2,4-dien-1-ylium)
C
cyclopropenyl anion (cycloprop-2-en-1-ide)
D
cyclopentadienyl anion (cyclopenta-2,4-dien-1-ide)
Answer: D
The cyclopentadienyl anion is planar and cyclic with 6 pi electrons (
4
n
+
2
,
n
=
1
). The cyclopentadienyl cation, cyclopropenyl anion and cyclobutadiene each have 4 pi electrons and are antiaromatic.
Practice General Organic Chemistry I: Electronic Effects
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