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NEET levelSingle correct optionDifficulty 1 of 3g1031

In benzene, which statement about the carbon-carbon bonds is correct?

  1. AAll six C-C bonds are pure double bonds.
  2. BAll six C-C bonds are equal in length, intermediate between single and double bonds.
  3. CAll six C-C bonds are pure single bonds.
  4. DThree C-C bonds are single and three are double, with different lengths.

Answer: B

Benzene is a resonance hybrid of the two Kekule structures, and the pi electrons are delocalised over the ring. So all C-C bonds have the same length (about 139 pm), between a single (154 pm) and a double (134 pm) bond.
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