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JEE Main levelSingle correct optionDifficulty 2 of 3g1017

In 1-chloropropane, , the carbon atoms are numbered C-1 (bonded to Cl), C-2 and C-3 (the methyl carbon). The order of partial positive charge on them is

  1. AC-3 > C-2 > C-1
  2. BC-1 = C-2 = C-3
  3. CC-1 > C-2 > C-3
  4. DC-2 > C-1 > C-3

Answer: C

Cl withdraws sigma electrons through the -I effect. The polarisation is largest on the adjacent carbon and falls off along the chain, so C-1 > C-2 > C-3.
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