JEE Main levelSingle correct optionDifficulty 2 of 3g1017
In 1-chloropropane, CHX3−CHX2−CHX2−Cl, the carbon atoms are numbered C-1 (bonded to Cl), C-2 and C-3 (the methyl carbon). The order of partial positive charge on them is
AC-3 > C-2 > C-1
BC-1 = C-2 = C-3
CC-1 > C-2 > C-3
DC-2 > C-1 > C-3
Answer: C
Cl withdraws sigma electrons through the -I effect. The polarisation is largest on the adjacent carbon and falls off along the chain, so C-1 > C-2 > C-3.