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General Organic Chemistry I: Electronic Effects
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Inductive effect
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g1012
Which of the following groups are electron-withdrawing by the -I effect relative to hydrogen?
A
−
NO
X
2
B
−
C
(
CH
X
3
)
X
3
C
−
CN
D
−
O
X
−
Answer: A, C
−
NO
X
2
and
−
CN
pull sigma electrons toward themselves (-I).
−
O
X
−
and
−
C
(
CH
X
3
)
X
3
release electron density (+I).
Practice General Organic Chemistry I: Electronic Effects
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