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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3eq201

mol of is dissolved in dilute . Consider titration with (oxidises both and oxalate completely) and with (assume it oxidises only ). Which statements are correct?

  1. AThe oxalate part consumes two-thirds of the total volume.
  2. BThe solution needed for the present is .
  3. CComplete oxidation requires of the solution.
  4. DThe part alone consumes of the solution.

Answer: A, B, C

Total meq ; is , so . Fe alone is 10.0 meq: of (not 200) or of dichromate. Oxalate is 20.0 of 30.0 meq, i.e. two-thirds.
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