JEE Advanced levelSingle correct optionDifficulty 3 of 3eq197
10.0mL of a hydrogen peroxide solution is diluted to 100.0mL. A 20.0mL portion of the diluted solution needs 15.0mL of 0.0200M acidified KMnOX4. The volume strength of the original solution (volume of OX2 at STP given by 1mL on decomposition; molar volume 22.4L) is:
A0.42V
B4.2V
C8.4V
D2.1V
Answer: B
In the 20.0mL portion, HX2OX2=15.0×0.0200×5/2=0.750 mmol, so the diluted solution is 0.0375M and the original is 0.375M. Since 2HX2OX2→OX2, 1M corresponds to 11.2V. Volume strength =0.375×11.2=4.2V.