NEET levelSingle correct optionDifficulty 1 of 3eq076
The equivalent mass of NaX2SX2OX3⋅5HX2O (molar mass 248gmol−1) in its reaction with iodine, 2SX2OX3X2−+IX2SX4OX6X2−+2IX−, is
A124
B62
C496
D248
Answer: D
Two thiosulphate ions lose two electrons in total (average S oxidation state +2 to +2.5), so the n-factor per SX2OX3X2− is 1. Equivalent mass = 248/1 = 248 g/equiv.