JEE Main levelSingle correct optionDifficulty 2 of 3eq045
0.756g of oxalic acid dihydrate HX2CX2OX4⋅2HX2O (molar mass 126gmol−1) is dissolved in water and made up to 100mL. A 10.0mL portion needs 12.5mL of a NaOH solution for complete neutralisation (to NaX2CX2OX4). The molarity of the NaOH is:
A0.048 M
B0.192 M
C0.077 M
D0.096 M
Answer: D
Moles of acid in 10.0mL=0.756/126×0.1=0.00060; with n=2, equivalents =0.00120. Moles of NaOH (n=1) in 12.5mL equal this, so M=0.00120/0.0125=0.096M.