JEE Advanced levelSingle correct optionDifficulty 3 of 3ev101
A chain started by a Cl atom propagates through the two steps Cl+OX3ClO+OX2 and ClO+OCl+OX2. The chain ends when Cl reacts with methane, Cl+CHX4HCl+CHX3. Which statement about this termination is correct?
AIt regenerates Cl atoms from methane
BIt converts the active Cl atom into the inactive reservoir HCl, so the chain length is limited
CIt produces ozone from HCl
DIt makes the chain faster by producing ClO
Answer: B
Cl abstracts a hydrogen atom from methane, forming HCl, which is a reservoir species that does not react with ozone. The Cl atom is therefore removed from the cycle, which ends the chain (unless HCl later reacts to give Cl again).