JEE Advanced levelOne or more correct optionsDifficulty 3 of 3ev050
A gas X is colourless with a pungent smell, turns acidified KX2CrX2OX7 green and is emitted on burning sulphur containing coal. Which statements about X are correct?
AX is a neutral oxide like CO.
BX acts as a reducing agent in this test.
CSulphur is in the +4 oxidation state in X.
DIn air, particulates catalyse oxidation of X to SOX3.
Answer: B, C, D
X is SOX2 with S at +4. It reduces Cr(VI) to green Cr(III), is oxidised to SOX3 in air (particulates catalyse this) and is an acidic oxide, giving HX2SOX3 with water. It is not a neutral oxide.