JEE Advanced levelSingle correct optionDifficulty 3 of 3ev036
In urban air containing hydrocarbons, ozone accumulates to harmful levels in photochemical smog. The best explanation is that
Aperoxy radicals, formed from hydrocarbons, oxidise NO to NOX2 without consuming OX3
Bhydrocarbons absorb sunlight and directly convert OX2 into OX3
Chydrocarbons react with NOX2 to give back NX2 and OX2
Dperoxy radicals react with OX3 to give NO
Answer: A
Hydrocarbons are oxidised to radicals, e.g. ROX2⋅+NORO⋅+NOX2. This converts NO to NOX2 by a path that does not use up ozone, so the NOX2 can photolyse again so the ozone formed in O+OX2OX3 is not removed by NO and accumulates.