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JEE Advanced levelSingle correct optionDifficulty 3 of 3ev036

In urban air containing hydrocarbons, ozone accumulates to harmful levels in photochemical smog. The best explanation is that

  1. Aperoxy radicals, formed from hydrocarbons, oxidise to without consuming
  2. Bhydrocarbons absorb sunlight and directly convert into
  3. Chydrocarbons react with to give back and
  4. Dperoxy radicals react with to give

Answer: A

Hydrocarbons are oxidised to radicals, e.g. . This converts to by a path that does not use up ozone, so the can photolyse again so the ozone formed in is not removed by and accumulates.
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