JEE Main levelSingle correct optionDifficulty 2 of 3ec14
Given E∘ values: FeX3+/FeX2+=0.77, CuX2+/Cu=0.34, AgX+/Ag=0.80, ZnX2+/Zn=−0.76V. Which pair cannot coexist in an aqueous solution under standard conditions?
AFeX3+ and Cu(s)
BFeX2+ and CuX2+
CZnX2+ and CuX2+
DAgX+ and FeX3+
Answer: A
A reaction is spontaneous when the oxidant has the higher E∘. FeX3+ (0.77) will oxidise Cu metal (0.34): 2FeX3++Cu2FeX2++CuX2+, E∘=0.43V. The other pairs are either both oxidised forms with no reductant present or do not react.