NEET levelSingle correct optionDifficulty 1 of 3ec047
A galvanic cell has Ecell∘=0.50V and the cell reaction involves 3 electrons. Taking F=96500Cmol−1, ΔrG∘ of the cell reaction is
A−144.75kJmol−1
B−48.25kJmol−1
C+144.75kJmol−1
D−144.75Jmol−1
Answer: A
ΔrG∘=−nFEcell∘=−3×96500×0.50=−144750Jmol−1=−144.75kJmol−1. A positive EMF corresponds to a negative Gibbs energy change (spontaneous). Option B forgets the factor n; option D has wrong units.