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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3df164

Which of the following statements about the spectra and magnetism of trivalent lanthanide ions are correct?

  1. AThe spin-only formula reproduces the observed moments of all ions accurately.
  2. BTheir colours arise from f-f transitions.
  3. CTheir absorption bands are sharper than d-d bands because the 4f orbitals are shielded by the filled 5s and 5p subshells.
  4. D is colourless and diamagnetic.

Answer: B, C, D

f-f transitions give the colours, and shielding of 4f electrons by 5s and 5p makes the bands narrow. The spin-only formula fails for many ions because of large orbital contributions. is , which is colourless and diamagnetic.
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