JEE Main levelSingle correct optionDifficulty 2 of 3df138
Assertion (A): Aqueous FeX2+ is paramagnetic with a spin-only magnetic moment of 4.90 BM.
Reason (R): In [Fe(HX2O)X6]X2+, the 3d6 electrons are all paired because water is a strong-field ligand.
AA is true but R is false
BBoth A and R are true and R is the correct explanation of A
CBoth A and R are true but R is not the correct explanation of A
DA is false but R is true
Answer: A
FeX2+ is 3d6. Water is a weak-field ligand, so the complex is high spin (t2g4eg2) with 4 unpaired electrons and μ=4.90BM. A is true, but R is false.