JEE Advanced levelOne or more correct optionsDifficulty 3 of 3df105
Select the correct statements about permanganate and manganate.
AMnOX4X2− (KX2MnOX4) is paramagnetic with one unpaired electron
BIn neutral medium MnOX4X− accepts 3 electrons per ion, giving MnOX2
CHeating solid KMnOX4 at 513 K gives KX2MnOX4, MnOX2 and OX2
DIn strongly alkaline medium MnOX4X− accepts 5 electrons per ion
Answer: A, B, C
(a) Mn(VI) is d1, so one unpaired electron: true. (b) +7→+4 is 3 electrons: true. (c) 2KMnOX4→KX2MnOX4+MnOX2+OX2: true. (d) False: in strongly alkaline medium only MnOX4X−+e−→MnOX4X2− occurs (1 electron).