MolSynapse
question bank
All chapters
NEET
JEE
Practice
MolSynapse
/
Question bank
/
Coordination Compounds
/
Crystal field theory: splitting, CFSE, spectrochemical series
JEE Main level
Single correct option
Difficulty 2 of 3
cc028
Using CFSE
t
e
t
=
(
−
0.6
n
e
+
0.4
n
t
2
)
Δ
t
and ignoring pairing energy, the CFSE of the tetrahedral complex
[
NiCl
X
4
]
X
2
−
is
A
−
1.6
Δ
t
B
−
0.8
Δ
t
C
−
0.4
Δ
t
D
−
1.2
Δ
t
Answer: B
Ni(II) is
d
8
, and tetrahedral
d
8
is
e
4
t
2
4
. CFSE
=
−
0.6
×
4
+
0.4
×
4
=
−
2.4
+
1.6
=
−
0.8
Δ
t
.
Practice Coordination Compounds
More on Crystal field theory: splitting, CFSE, spectrochemical series
Previous question
Next question
More questions on Crystal field theory: splitting, CFSE, spectrochemical series
Take [Co(NH3)6]^3+ to be low spin and ignore pairing energy. Its CFSE in units of Delta_o is
JEE Main level
Which of the following octahedral aqua ions is expected to be colourless?
JEE Main level
Among [CoF6]^3-, [Co(NH3)6]^3+, [Co(en)3]^3+ and [Co(CN)6]^3-, the complex that absorbs light of the longest wavelength is
JEE Main level
Assertion: Tetrahedral complexes of first-row transition metals are almost always high spin. Reason: For the same metal and ligands Delta_t ...
JEE Main level
Take [NiCl4]^2- as tetrahedral and [Ni(CN)4]^2- as square planar. Their spin-only magnetic moments (BM) are respectively
JEE Main level
Assume weak-field ligands give high spin, cyanide gives low spin, and take [Co(NH3)6]^3+ as low spin. Which complex has the highest spin-onl...
JEE Main level