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Crystal field theory: splitting, CFSE, spectrochemical series
JEE Main level
Single correct option
Difficulty 2 of 3
cc023
Use
μ
=
n
(
n
+
2
)
BM. Cyanide is a strong-field ligand, so
[
Fe
(
CN
)
X
6
]
X
3
−
is low spin. Its spin-only magnetic moment is
A
0 BM
B
2.83 BM
C
1.73 BM
D
5.92 BM
Answer: C
Fe is
+
3
(
d
5
). In the low spin case all five electrons go into
t
2
g
as
t
2
g
5
, leaving
n
=
1
unpaired electron.
μ
=
1
×
3
=
1.73
BM.
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