JEE Main levelSingle correct optionDifficulty 2 of 3cc012
Using EAN =Z−(oxidation state)+2×(number of monodentate ligands), and the nearest noble gas being krypton (Z=36), which complex ion has an effective atomic number equal to 36? (Z: Cr 24, Fe 26, Co 27, Ni 28)
A[Co(NHX3)X6]X3+
B[Ni(NHX3)X6]X2+
C[Fe(CN)X6]X3−
D[Cr(NHX3)X6]X3+
Answer: A
EAN for [Co(NHX3)X6]X3+ is 27−3+12=36. For the others: [Fe(CN)X6]X3− is 26−3+12=35, [Cr(NHX3)X6]X3+ is 24−3+12=33 and [Ni(NHX3)X6]X2+ is 28−2+12=38.