Numerical answer type, tolerance 0.5.
Answer: 12
The compound shown is sodium lauryl sulphate, anion C12H25OSO3-. The chain has CH3 (1), the OCH2 (1) and ten other CH2 groups, each topologically different from the others (no symmetry in an unbranched chain). Total 1 + 1 + 10 = 12, confirmed with RDKit canonical ranks.