MolSynapsequestion bank
MolSynapse / Question bank / Chemistry in Everyday Life / Cleansing agents: soaps and detergents
JEE Advanced levelSingle correct optionDifficulty 3 of 3el197

Sodium stearate solution and sodium dodecylbenzenesulphonate solution are each acidified with dilute HCl. Only the first turns turbid. The best explanation is that

  1. AHCl reacts with the benzene ring of the detergent to make it more soluble
  2. Bstearic acid is a weak acid, so the stearate ion is protonated to insoluble , whereas the sulphonic acid is a strong acid and its anion stays ionised
  3. Cthe sulphonate ion is a stronger base than stearate and consumes all the
  4. Dstearate ions are oxidised by HCl, but sulphonate ions are not

Answer: B

The anion of a weak acid picks up a proton: , and the neutral long-chain acid is insoluble. Alkylbenzenesulphonic acid is strongly acidic, so its anion stays ionised and soluble. The anion of a weaker acid is the stronger base, which is stearate, not sulphonate.
Practice Chemistry in Everyday Life More on Cleansing agents: soaps and detergents

More questions on Cleansing agents: soaps and detergents