JEE Advanced levelSingle correct optionDifficulty 3 of 3el197
Sodium stearate solution and sodium dodecylbenzenesulphonate solution are each acidified with dilute HCl. Only the first turns turbid. The best explanation is that
AHCl reacts with the benzene ring of the detergent to make it more soluble
Bstearic acid is a weak acid, so the stearate ion is protonated to insoluble CX17HX35COOH, whereas the sulphonic acid is a strong acid and its anion stays ionised
Cthe sulphonate ion is a stronger base than stearate and consumes all the HX+
Dstearate ions are oxidised by HCl, but sulphonate ions are not
Answer: B
The anion of a weak acid picks up a proton: CX17HX35COOX−+HX+CX17HX35COOH, and the neutral long-chain acid is insoluble. Alkylbenzenesulphonic acid is strongly acidic, so its anion stays ionised and soluble. The anion of a weaker acid is the stronger base, which is stearate, not sulphonate.