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Monitoring reactions by pressure, titration and optical rotation
JEE Main level
Single correct option
Difficulty 2 of 3
ck126
A first-order reaction
A
(
g
)
2
B
(
g
)
starts with pure A at 100 kPa in a rigid vessel. After exactly three half-lives the total pressure (in kPa) is
A
200.0
B
175.0
C
112.5
D
187.5
Answer: D
After three half-lives
p
A
=
100/8
=
12.5
kPa and A reacted = 87.5 kPa, giving 175.0 kPa of B.
P
=
12.5
+
175.0
=
187.5
kPa.
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