JEE Main levelSingle correct optionDifficulty 2 of 3ce188
For NX2(g)+3HX2(g)2NHX3(g), ΔH=−92kJ. The temperature of the equilibrium mixture in a rigid vessel is raised. Which statement is correct?
AThe amount of NHX3 increases and Kc increases
BThe amount of NHX3 is unchanged because the volume is fixed
CThe amount of NHX3 decreases and Kc decreases
DThe amount of NHX3 decreases but Kc is unchanged
Answer: C
The forward reaction is exothermic, so heating favours the reverse direction and NHX3 decreases. Kc is a function of temperature, and for ΔH<0 it decreases as T rises.