Which of the following carbonates decomposes at the lowest temperature?

Thermal stability of Group $2$ carbonates increases down the group. The small $\mathrm{Be}{}^{2+}$ polarises the carbonate ion most strongly, which weakens a C-O bond and favours loss of $\mathrm{CO}{}_2$. So $\mathrm{BeCO}{}_3$ is the least stable.