NEET levelSingle correct optionDifficulty 1 of 3cb176
Ethanol (b.p. 78∘C) boils much higher than dimethyl ether (b.p. −24∘C) although both are CX2HX6O. This is due to
Aionic character of the C-O bond in ethanol
Bintermolecular hydrogen bonding in ethanol
Cstronger London forces in dimethyl ether
Da higher molar mass of ethanol
Answer: B
The two are isomers with the same molar mass, so dispersion forces are comparable. Ethanol has an O-H group and forms intermolecular hydrogen bonds, while dimethyl ether has no O-H and cannot. This raises the boiling point of ethanol.