JEE Advanced levelSingle correct optionDifficulty 3 of 3cb055
The heat of hydrogenation of cyclohexene is −120kJmol−1 and that of benzene is −208kJmol−1. The resonance energy of benzene, in kJmol−1, estimated with this data is
A88
B120
C152
D240
Answer: C
Hypothetical cyclohexatriene with three isolated double bonds would release 3×120=360kJmol−1. The measured value is 208, so resonance energy =360−208=152kJmol−1.