JEE Advanced levelSingle correct optionDifficulty 3 of 3cb031
Assertion (A): IClX4X− is square planar.
Reason (R): The central iodine atom in IClX4X− has four bond pairs and no lone pair.
ABoth A and R are true and R is the correct explanation of A
BBoth A and R are true but R is not the correct explanation of A
CA is true but R is false
DA is false but R is true
Answer: C
Iodine in IClX4X− has (7+4+1)/2=6 electron pairs: 4 bond pairs and 2 lone pairs. The lone pairs sit trans to each other, so the ion is square planar. A is true but R is false.