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NEET levelSingle correct optionDifficulty 1 of 3co262

The acid shown has . Which of the structures A to D is the strongest acid?

  1. AStructure A
  2. BStructure B
  3. CStructure C
  4. DStructure D

Answer: B

The reference is ethanoic (acetic) acid. Each additional chlorine on the alpha carbon exerts a -I effect and stabilises the carboxylate: pKa 4.76, 2.86, 1.29, 0.65. Hence trichloroethanoic acid is the strongest.
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