NEET levelSingle correct optionDifficulty 1 of 3co262
The acid shown has pKa=4.76. Which of the structures A to D is the strongest acid?
AStructure A
BStructure B
CStructure C
DStructure D
Answer: B
The reference is ethanoic (acetic) acid. Each additional chlorine on the alpha carbon exerts a -I effect and stabilises the carboxylate: pKa 4.76, 2.86, 1.29, 0.65. Hence trichloroethanoic acid is the strongest.