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JEE Main levelOne or more correct optionsDifficulty 2 of 3co196

Which of the following acids lose readily on simple warming to about 100-150 C?

  1. Abenzoic acid
  2. B3-oxobutanoic acid
  3. C2,2-dimethylpropanoic acid
  4. Dpropanedioic acid

Answer: B, D

Only acids with a carbonyl group beta to the carboxyl group decarboxylate easily by the cyclic transition state: 3-oxobutanoic acid and propanedioic acid. Benzoic acid and 2,2-dimethylpropanoic acid need soda lime or more drastic conditions.
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