JEE Main levelSingle correct optionDifficulty 2 of 3co187
1-(4-Methylphenyl)ethanone, p-CHX3−CX6HX4−COCHX3, is treated with excess IX2 and aqueous NaOH, warmed, and then acidified. The carboxylic acid formed is
Abenzoic acid
B4-methylbenzoic acid
Cbenzene-1,4-dicarboxylic acid
Dphenylethanoic acid
Answer: B
A methyl ketone undergoes the haloform reaction: the COCHX3 group is converted to COOX− with loss of CHIX3. The ring methyl group is untouched under these conditions. Acidification gives 4-methylbenzoic acid.