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JEE Main levelSingle correct optionDifficulty 2 of 3co148

Cyclohexanol is heated with aluminium tert-butoxide in excess propanone. This Oppenauer oxidation gives

  1. Ahexanedioic acid
  2. Bcyclohexene
  3. Ccyclohexane
  4. Dcyclohexanone

Answer: D

Oppenauer oxidation is the reverse of MPV reduction: a secondary alcohol is oxidised to a ketone by hydride transfer to the excess propanone. Cyclohexanol gives cyclohexanone, not an acid.
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