JEE Advanced levelSingle correct optionDifficulty 3 of 3co101
Benzaldehyde is heated with aqueous-alcoholic KCN to give P. P is treated with NaBHX4 in methanol (ketone reduction, then work-up) to give Q. Q is
A1,2-diphenylethanone
B1,2-diphenylethane-1,2-diol
C1,2-diphenylethane-1,2-dione
D2-hydroxy-1,2-diphenylethanone
Answer: B
The benzoin condensation gives P, CX6HX5CH(OH)COCX6HX5. NaBHX4 reduces the ketone C=O to a secondary alcohol. Q is CX6HX5CH(OH)CH(OH)CX6HX5, 1,2-diphenylethane-1,2-diol.