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Aldehydes, Ketones and Carboxylic Acids
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Preparation of aldehydes and ketones
JEE Main level
Single correct option
Difficulty 2 of 3
co044
Anisole (
C
X
6
H
X
5
OCH
X
3
) reacts with ethanoyl chloride and anhydrous
AlCl
X
3
. The major product is
A
methyl benzoate
B
1-(4-methoxyphenyl)ethan-1-one
C
1-(3-methoxyphenyl)ethan-1-one
D
2-methoxy-1-phenylethan-1-one
Answer: B
Friedel-Crafts acylation is electrophilic substitution by
CH
X
3
CO
X
+
. The methoxy group is a strong ortho/para director and the para product is major.
Practice Aldehydes, Ketones and Carboxylic Acids
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