JEE Advanced levelSingle correct optionDifficulty 3 of 3bm046
A linear polymer of D-glucose joined only by alpha-1,4 links has molar mass 16200gmol−1 (treat it as exactly n×162, the mass of n units of CX6HX10OX5, ignoring the end groups). The number of glycosidic bonds hydrolysed on complete hydrolysis is
A98
B99
C100
D101
Answer: B
The number of units is n=16200/162=100. A linear chain of n units has n−1 glycosidic bonds, so 99 bonds are broken.