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JEE Advanced levelSingle correct optionDifficulty 3 of 3bm037

Which aldohexose gives an optically inactive (meso) aldaric acid on oxidation with hot dilute nitric acid?

  1. AD-mannose
  2. BD-fructose
  3. CD-glucose
  4. DD-galactose

Answer: D

The aldaric acid from galactose has a mirror plane because the C-2/C-5 and C-3/C-4 pairs are mirror images. Glucose and mannose give optically active aldaric acids, and fructose is cleaved rather than giving an aldaric acid.
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