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Atomic Structure
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Hydrogen spectrum and spectral series
JEE Advanced level
Numerical answer
Difficulty 3 of 3
as097
Use
R
H
=
1.097
×
1
0
7
m
−
1
. The
n
=
3
→
n
=
2
line of a certain hydrogen-like ion is observed at
72.9
nm
. Find the atomic number
Z
of the ion (nearest integer).
Numerical answer type, tolerance 0.1.
Answer: 3
1/
λ
=
Z
2
R
H
(
1/4
−
1/9
)
=
5
Z
2
R
H
/36
, so
Z
2
=
36/
(
5
R
H
λ
)
=
9.003
. Hence
Z
≈
3.00
, i.e.
Z
=
3
(Li2+).
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