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JEE Main levelSingle correct optionDifficulty 2 of 3ap243

The alcohol shown is heated with concentrated at 443 K. Which structure is the major alkene (Saytzeff product, the more stable geometrical isomer)?

  1. AStructure A
  2. BStructure B
  3. CStructure C
  4. DStructure D

Answer: B

The alcohol is butan-2-ol. E1 elimination follows Saytzeff's rule and gives the more substituted alkene, but-2-ene. Of its two geometrical isomers, the trans (E) form is more stable because the methyl groups are far apart, so it predominates over cis-but-2-ene and but-1-ene.
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