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JEE Main levelOne or more correct optionsDifficulty 2 of 3ap194

Which statements about pinacol, , are correct?

  1. AIt is obtained by bimolecular reduction of propanone with and water
  2. BPeriodic acid cleaves it to two moles of propanone
  3. CDilute acid converts it into 3,3-dimethylbutan-2-one
  4. D in oxidises it to 2,3-dimethylbutane-2,3-dione

Answer: A, B, C

Pinacol is made by pinacol coupling of acetone, cleaved by at the vicinal diol to two , and rearranges to pinacolone with acid. Both carbinol carbons are tertiary and carry no hydrogen, so PCC cannot oxidise it to a diketone.
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