JEE Main levelSingle correct optionDifficulty 2 of 3ap189
1,1-Diphenylethane-1,2-diol, (CX6HX5)X2C(OH)−CHX2OH, is treated with dilute HX2SOX4. The rearranged product is
A1,2-diphenylethan-1-one
B2,2-diphenyloxirane
C2,2-diphenylethanal
Dbenzophenone
Answer: C
The OH on the diphenyl carbon is lost, giving the highly stabilised (CX6HX5)X2CX+−CHX2OH. The only migrating group on the neighbouring carbon is hydrogen, so H shifts and the product is (CX6HX5)X2CH−CHO, 2,2-diphenylethanal.