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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3ap160

In each of the following pairs a test is suggested to distinguish the two compounds. Select all pairs where the test works.

  1. Abutan-1-ol and butan-2-ol: Tollens reagent
  2. Bethanol and methanol: warm with
  3. Cphenol and phenylmethanol: neutral
  4. Dpropan-1-ol and propan-2-ol: Lucas reagent at room temperature, observed for 5 to 10 minutes

Answer: B, C, D

Ethanol gives yellow while methanol does not. Propan-2-ol becomes turbid within about 5 minutes with Lucas reagent while propan-1-ol stays clear, and phenol gives a violet colour whereas phenylmethanol does not. Neither butanol reacts with Tollens reagent, so it cannot distinguish them.
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