JEE Main levelSingle correct optionDifficulty 2 of 3ap153
Which of the following diols does NOT react with periodic acid, HIOX4?
Aethane-1,2-diol
Bpropane-1,2-diol
Cpropane-1,2,3-triol
Dbutane-1,3-diol
Answer: D
Periodic acid cleaves the C−C bond between two adjacent carbons each bearing an −OH group (vicinal diols). In butane-1,3-diol the hydroxyl groups are on carbons 1 and 3, which are not adjacent, so no cleavage occurs.