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Phenol is heated with and aqueous , and the mixture is then acidified with . The major product is

  1. A4-hydroxybenzaldehyde
  2. B2-hydroxybenzaldehyde
  3. C2-hydroxybenzoic acid
  4. Dbenzaldehyde

Answer: B

This is the Reimer-Tiemann reaction. Dichlorocarbene attacks the phenoxide ion mainly at the ortho position, and hydrolysis of the group followed by acidification gives 2-hydroxybenzaldehyde (salicylaldehyde); the para isomer is only minor.
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